Encapsulated reactant and process

ABSTRACT

An encapsulated reactant(s) having at least one encapsulant and at least one reactant, and methods of making and using the encapsulated reactant(s), are is presently provided. An outermost encapsulant is substantially nonreacting, impermeable and nondissolving with water. The reactant(s) contribute to at least one reaction with contaminants in environmental media rendering the environmental media less harmful.

CROSS-REFERENCE TO RELATED APPLICATIONS

The instant application is a continuation-in-part of U.S. patentapplication Ser. No. 12/269,520 now U.S. Pat. No. 10,335,757) and U.S.patent application Ser. No. 15/450,369. U.S. patent application Ser. No.12/269,520 was filed on Nov. 12, 2008, and is a continuation-in-part ofU.S. patent application Ser. No. 12/169,434, filed Jul. 8, 2008, whichin turn is a continuation of and claims priority to U.S. patentapplication Ser. No. 11/072,118, filed Mar. 4, 2005 (now U.S. Pat. No.7,431,849), which in turn claims priority to U.S. ProvisionalApplication Ser. No. 60/550,799, filed Mar. 5, 2004, all of which arehereby incorporated by reference in their entirety. U.S. patentapplication Ser. No. 15/450,369 was filed on Mar. 6, 2017, and is adivisional of and claims the benefit of U.S. patent application Ser. No.14/024,046 now U.S. Pat. No. 9,611,421), filed on Sep. 11, 2013, whichis a divisional of and claims the benefit of U.S. patent applicationSer. No. 13/088,217, filed Apr. 15, 2011, which is a continuation of andclaims the benefit of U.S. patent application Ser. No. 12/169,434 filedon Jul. 8, 2008, which in turn is a continuation of U.S. patentapplication Ser. No. 11/072,118 filed on Mar. 4, 2005, issued as U.S.Pat. No. 7,431,849, all of which are hereby incorporated by reference intheir entirety.

FIELD OF INVENTION

The present invention relates to reactant(s), methods for making thereactant(s), and methods for the in situ and ex situ remediation ofhazardous organic compounds in soil, groundwater, and surface water.

BACKGROUND OF THE INVENTION

Discharges of hazardous organic compounds into the environment have ledto contamination of surface water, soil, and aquifers resulting inpotential public health problems and degradation of the land for futureuse. As used in this specification and appended claims, hazardousorganic compound means a chemical or substance that is either toxic orhighly toxic, an irritant, corrosive, a strong oxidizer, a strongsensitizer, combustible, either flammable or extremely flammable,dangerously reactive, pyrophoric, pressure-generating, a compressed gas,a carcinogen, a teratogen, a mutagen, a reproductive toxic agent, or issuspected of having adverse health effects on humans. In many cases,subsurface groundwater contaminant plumes may extend hundreds tothousands of feet from the source area of chemical release resulting inextensive contamination. These chemical contaminants may then betransported into drinking water sources, lakes, rivers, and evenbasements of homes.

The U.S. Environmental Protection Agency (USEPA) has established maximumconcentration limits (MCL's) for various hazardous organic compounds inwater and soils. For instance, stringent drinking water limits placed onmany solvent organic compounds in water can be as low as 0.005 μg/L(parts per billion).

The presence of hazardous organic compounds in subsurface soils, surfacewater, and groundwater is a well-documented and extensive problem. Thesource of these hazardous materials is often times from industry wherethe materials are released onto the soil surface or surface water oreven into the subsurface soil and/or groundwater through leaking storagetanks. Many, if not most, of these organic compounds are capable ofmoving through the soil under the influence of moving water, gravity, orcapillary action and serve as a source of groundwater contamination. Asused in this specification and appended claims, soil is to beinterpreted broadly to include all naturally occurring material foundbelow ground surface (e.g. silts, clays, sands, rock, karsts, organics,tills, etc.).

Soil, surface water, groundwater, and wastewater can become contaminatedby a variety of substances. The substances include, without limitation,volatile, semi-volatile, and non-volatile organic compounds. Commonexamples of such contaminates include PCBs, gasoline, oils, woodpreservative wastes, and other hazardous organic compounds. Such otherhazardous organic compounds may include, but not limited to, chlorinatedsolvents (such as trichloroethylene (TCE), vinyl chloride,tetrachloroethylene (PCE), dichloroethanes), ethylene dibromide,halobenzenes, polychlorinated biphenyls, acetone, ter-butyl alcohol,tert-butyl formate, and anilines. Additional contaminants includecompounds containing at least one oxidizable aliphatic or aromaticcompound and/or functional group (e.g. atrazine, benzene, butylmercaptan, chlorobenzene, chloroethylvinyl ether, chloromethyl methylether, chlorophenol, chrysene, cyanide ion or organic cyanides,dichlorophenol, dichlorobenzene, dichloroethane, dichloroethene,dichloropropane, dichloropropene, ethyl alcohol, ethylbenzene, ethyleneglycol, ethyl mercaptan, hydrogen sulfide, isopropyl alcohol, Lindane™,methylene chloride, methyl tert-butyl ether, naphthalene, nitrobenzene,nitrophenol, pentachlorophenol, phenanthrene, phenol, propylene,propylene glycol, Silvex™, Simazine™, sodium sulfide, tetrachloroethane,tetrachloroethene, toluene, trichlorobenzene, trichloroethane,trichloroethene, trichlorophenol, vinyl chloride, xylene, etc).

Contaminated soil, surface water and groundwater must be removed ortreated to make it less toxic and to meet USEPA requirements. There area variety of reactants and methods for treating contaminated soil,surface water, groundwater, and wastewater as discussed below.Peroxydisulfates have been reported as applied constituents for organiccarbon digestion or decomposition. Application methods include thermallyactivated persulfate oxidation in conjunction with an electro-osmosissystem to heat and transport persulfate anions into soils.Permanganate(s) and peroxygen(s) reactant(s) have also been reported asapplied constituents for oxidation of organic compounds. Peroxygencompound(s) applied independently or in conjunction with a metallic saltcatalyst(s) (complexed and not complexed; chelated and not chelated)have been shown to break down organic compounds within the soil,groundwater, and wastewater.

Groundwater and subsurface soil typically has been treated by injectingreactant(s), with or without a catalyst(s), within an aqueous mixture,slurry, or suspension into the subsurface. Injection into the subsurfaceis accomplished by gravity feed or the use of a pump(s) to increase wellhead pressure. This results in the subsurface dispersion of thereactant(s) within the area of the injection well.

Another method for in situ treatment of groundwater includes theexcavation of a trench at or beyond a subsurface plume of organic and/orinorganic contaminant(s). The trench is filled with reactant(s) and apermeable media(s) (i.e. sand) for the plume to flow through,subsequently reacting oxidizable organic and/or inorganic compounds thatcome into contact with the reactant(s).

The methods used for ex situ treatment or in situ treatment of surfacecontamination, water or soil, typically involves the direct applicationof the reactant(s) to the hazardous organic compound(s). In the case ofex situ surface soil treatment, the soil is often times mixed or tilledto ensure contact of the reactant(s) with the hazardous organiccompound(s).

Meeting USEPA cleanup criteria with these reactants and methods of theprior art has been found to be difficult, costly, and even impossible.With some of these current methods and reactants, there has beenquestionable showing that their application results in the effective orefficient removal of contaminants.

Current methods involving the use of peroxide group(s) (i.e. hydrogenperoxide) in conjunction with iron salt catalyst(s) have shown to berelatively inefficient, often resulting in incomplete contaminantoxidation. Hydrogen peroxide in particular has been found to lackpersistence in contaminated soils and groundwater due to rapiddissociation. Many of these current employed reactants are hazardous anddifficult to handle.

Recently, the use of permanganate(s) has been found to be a moreeffective oxidizing agent of certain hazardous organic compound(s).However, known methods of permanganate use to remediate a site requireexceedingly large quantities of permanganate(s) to overcome the naturaloxidant demand exerted by the soil, thereby limiting the percentageavailable for oxidizing the hazardous organic compound(s). Large amountsof permanganate(s) are thus required per unit of soil and groundwatervolume, limiting the application of this technology due to high cost.Additionally, a product of the permanganate(s) oxidation reaction issolid manganese dioxide which precipitates and clogs the soil oraquifer, resulting in a reduced permeability of the soil to water. Thisreduced permeability in turn reduces the hydraulic conductivity thereof,and thereby inhibiting oxidant access to the entire contaminated siteand rendering treatment of the soil and hazardous organic compoundsincomplete. Further disadvantages of using permanganate(s) alone and inlarge quantities for subsurface remediation includes the formation ofsoluble manganese compounds in groundwater that may exceed drinkingwater standards. For this and the foregoing reasons, attempts to date touse permanganate(s) for in situ remedial applications have not beenfully successful.

More recently, attempts have been made to resolve the disadvantagesassociated with the use of permanganate(s) by incorporatingpersulfate(s) oxidants into the in situ application, such as thosetechniques discussed in U.S. Pat. No. 6,474,908. The theory relied ontherein utilizes the persulfate(s) to satisfy the total oxidant demandof the selected environment (soil, water, sludge, etc.) and then followsup with the permanganate(s) to treat target hazardous organicconstituents. However, the total amount of permanganate(s) andpersulfate(s) required to treat a large area is still excessive and theextent to which the reactant(s) travel in the aquifer before being spentor reacted is insufficient.

Because of these limitations of art before the present invention, thereis a need for reactant(s) and methods of making reactant(s) for treatinghazardous organic contaminant(s) in soil, sludge, groundwater, surfacewater, and wastewater that do not require electro-osmosis, heat, orinefficient metallic catalyst(s). What is needed are materials andmethods of making the materials, wherein the materials react with thecontaminant(s) and persistent in the zone(s) having the contaminant(s)to provide improved characteristics for use in environmentalremediation.

SUMMARY OF THE INVENTION

The present invention provides reactants, methods of making reactants,and a method for treating hazardous organic contaminant(s) in soil,sludge, groundwater, surface water, and wastewater that does not requireelectro-osmosis, heat, or inefficient metallic catalyst(s), and mayprovide for easier handling, persistence in the zone(s) having thecontaminant(s), and reactivity with the contaminant(s) to form moreinnocuous materials.

The present invention relates to environmental reactant(s), process ofmaking environmental reactant(s), and process for the remediation ofsoil and/or water whether the contamination is a surface or subsurfacecontaminant. More specifically, the process of making the reactant(s)may provide reactant(s), suspended reactant(s), and/or encapsulatedreactant(s) and methods for controlling the release and/or distributionof the reactant(s) thus providing a means for remediation of soil,water, wastewater, and/or other environmental remediation and/ortreatment for in situ or ex situ processes.

The controlled release and/or distribution of the reactant(s) may bemanipulated via a suspending liquid and/or encapsulating coating whichtargets contaminants or specific organic compounds in the environmentalmedia being treated. Optionally, the reactant(s) made by the process ofthe present invention have a coating material thereabout providingsuitable protection of the reactant for treating the environmental mediawithout further encapsulation. The reactants may be oxidants, catalysts,chelants, transition metal amine complexes, combinations thereof, and/orother chemical constituents that effectuate a reaction with the targetedcompounds. The reaction between the encapsulated reactant(s) and thetargeted organic compounds renders the media being treated lesshazardous.

The suspension having reactant(s) may be comprised of reactant particlessuspended in a liquid. The liquid may have for example water,emulsifiers, surfactants, and/or other substances as are known in theart to substantially suspend the reactant(s) in a suspension or slurry.

The encapsulated reactant of the present invention may have a singlereactant contained within a single encapsulant, a plurality of reactantscontained within a single encapsulant, or a plurality of reactantscontained within a plurality of encapsulants. An outer encapsulantprovides for the targeting characteristic of the encapsulated reactantby masking, protecting, stabilizing, delaying, and/or controlling therelease and/or distribution of the reactant(s) contained within. In oneembodiment, the outer encapsulant is substantially oleophilic (i.e. hasa stronger affinity for oils rather than water) which saves the reactantfrom reacting with water or untargeted constituents in the media beingtreated. Additionally, the outer encapsulant is substantially reactive,permeable and/or dissolvable with at least one of the target compound(s)being remediated. Therefore, when the encapsulated reactant is contactedwith or exposed to the contaminants the coating dissolves, reacts, orabsorbs at least one of the targeted compound(s) found in the media andexposes at least one reactant to the targeted compounds where it mayreact. Optionally, the encapsulated reactants may be placed insuspension or in a slurry.

The encapsulated reactant may have an organic compound in the outermostencapsulant providing the desired oleophilic and hydrophobic,characteristics. The reactants contained within the encapsulant may be avariety of reactants such as catalysts, chelants, transition metal aminecomplexes, oxidants, or other reactants. The encapsulated reactant ofthe present invention may used to treat a variety of environmental mediahaving a variety of contaminants.

The coated and/or encapsulated reactants of the present invention, orthe reactants made by the process of the present disclosure, can be usedto treat soil, water, wastewater, silt, clay, etc. either in situ or exsitu. Different groups of encapsulated reactants having differentreactants, different coatings, and/or different outermost encapsulantscan be introduced into the media simultaneously, in discrete timeintervals, at the same location, or at alternate locations. Suchapplications provide a means for effectuating a single reaction ormultiple reactions, either in series or parallel toward a desired finalmedia state.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a cross-sectional view of an embodiment of the encapsulatedreactant of the present invention showing one reactant within anencapsulant.

FIG. 2 is a cross-sectional view of an embodiment of the encapsulatedreactant of the present invention showing a first and second reactantwithin a first and second encapsulant respectively.

FIG. 3 is a cross-sectional view of an embodiment of the encapsulatedreactant of the present invention showing a plurality or reactantswithin a plurality of encapsulants.

DETAILED DESCRIPTION OF THE INVENTION

The present invention provides encapsulated reactant(s), methods formaking coated, suspended, and/or encapsulated reactant(s), and methodsfor controlling the release and/or distribution of one or more reactantsthat provide for methods of soil, water, water treatment, and/or otherenvironmental remediation and/or treatment. The term water as usedherein refers to water in a broad sense and incorporates naturalsolutes. Water is considered to be a universal solvent and has hardness,metals, and a variety of minerals and salts naturally dissolved and/orionized therein. Therefore, water includes solutes except for selectedcontaminants and inerts. The encapsulated reactants of the presentinvention, or the coated, suspended, and/or encapsulated reactants madeby the disclosed process, may be used in in situ or ex situ processes.The controlled release and/or distribution of the reactant(s) may bemanipulated via one or more suspending liquids, coating materials,and/or encapsulating coating to target contaminants or specific organiccompounds in the media being treated. The reactants may be oxidants,catalysts, chelants, transition metal amine complexes, combinationsthereof, and/or other constituents that effectuate an initial,intermediate, and/or final reaction with the organic compound(s) beingtargeted. The reaction between the reactant(s) and the targeted organiccompounds causes the media being treated to have less hazardouscharacteristics. As used herein, the term “encapsulated” means having aform of protective enclosure and includes all forms of encapsulants andcoatings and includes micro-encapsulants. The encapsulated reactant(s)embodiments made by the process of the present invention are depicted inthe various FIGS. which are selected solely for the purpose ofillustrating examples of encapsulated reactant(s) made by the process ofthe present invention. Other and different reactant(s), encapsulated andnon-encapsulated, may be made by the process and utilize the inventivefeatures described herein. Reference to the Figures showing severalembodiments of products made by the process of the present invention ismade to describe the presently claimed invention and not to limit thescope of the claims herein.

FIG. 1 shows a cross-sectional view of encapsulated reactant 10, anembodiment of a reactant made by the process of the present inventionshowing one reactant 11 within encapsulant 12. Outer encapsulant 12provides for the targeting of organic constituents within the mediabeing treated by masking, protecting, stabilizing, delaying, and/orcontrolling the release and/or distribution of reactant 11. Targeting isaccomplished by having reactant 11 substantially isolated from the mediaand released or exposed to the contaminants or targeted organiccompounds when encapsulated reactant 10 encounters the contaminantswithin the media being treated. Thus, encapsulant 12 saves reactant 11from reacting with water or untargeted constituents in the media beingtreated so that reactant 11 remains substantially unreacted untilcontacting the targeted constituents. Therefore, reactant 11 isavailable for breaking down the targeted constituents when encapsulatedreactant 10 encounters the targeted constituents within the media beingtreated.

The outer surface of outer encapsulant 12 contacts the media beingtreated and the inner surface of encapsulant 12 contacts reactant 11.Therefore, encapsulant 12 needs be substantially nonreacting,impermeable and/or nondisolving with the media being treated andreactant 11 (i.e., if media is water then encapsulant 12 issubstantially water resistant). Additionally, encapsulant 12 needs besubstantially reactive, permeable and/or dissolvable with at least oneof the target organic compound(s) being treated. Thus, the compositionof encapsulant 12 depends on the composition of reactant 11, the mediabeing treated, and the targeted constituents.

Typically, in in situ remediation the media being treated is eitherwater or has water moving within, such as soil. In this mediaenvironment outer encapsulant 12 needs be substantially nonreacting,impermeable and/or nondissolving with water. At the same time,encapsulant 12 needs be soluble, reactive, and/or permeable to at leastone of the targeted compound(s) found in the media or environment beingtreated. The targeted constituents being remediated typically have atleast one organic compound and therefore encapsulant 12 typically issubstantially soluble, reactive, and/or permeable to at least onetargeted organic compound within the zone of contamination in the media.At least one targeted organic compound can substantially permeate, reactwith, or dissolve encapsulant 12.

Encapsulant 12 is characterized by having one or more of a plurality ofmechanisms for releasing and/or contacting reactant 11 with at least onetargeted compound. One mechanism in which encapsulant 12 may exposereactant 11 to targeted compounds is where at least one targeted organiccompound permeates encapsulant 12 causing an internal pressure ofencapsulated reactant 10 to reach a level suitable for reverse osmosis,dispersing reactant 11 to the zone of contamination. A second mechanisminvolves encapsulant 12 dissolving and/or rupturing with at least onetargeted organic compound releasing the encapsulated compounds orreactant 11 to the zone of contamination. Additionally, a “chemicaltrigger” can be incorporated within encapsulant 12 to allow foraccelerated degradation of the encapsulant 12 and/or release of reactant11 upon contact with the targeted compound groups being treated. Thethickness, permeability, and/or composition of encapsulant 12 can beadjusted to control the rate at which at least one targeted compoundpenetrates, dissolves, and/or reacts with encapsulant 12 therebydistributing and/or diffusing reactant 11. Additionally, encapsulant 12may be designed to sustain its characteristics for a period of time(days, weeks, or even months) when in contact with water. Thischaracteristic of encapsulant 12 allows unreacted encapsulated reactants10 to dissipate in the event they are not contacted with a targetedcompound. Furthermore, encapsulant 12 may have the characteristic of notdissolving in a targeted compound or water, at least for an extendedperiod of time, but being permeable to targeted compounds. Such anembodiment allows encapsulated reactant 10 to persist for an extendedperiod of time allowing the targeted compounds to permeate encapsulant12 and react with reactant 11. The foregoing mechanisms and embodimentsof the encapsulated reactant of the present invention are provided asdescriptive examples only and are not to serve as limiting the claimsherein.

Environmental remediation, water treatment, and/or wastewater treatmentoften seeks to, via at least the final reaction, oxidize contaminants orcompounds containing at least one oxidizable aliphatic or aromaticcompound and/or functional group (e.g., chlorinated organics, aliphaticorganics, aromatic organics, etc.). Examples include, but are notlimited to, atrazine, benzene, butyl mercaptan, chlorobenzene,chloroethylvinyl ether, chloromethyl methyl ether, chlorophenol,chrysene, cyanide ion or organic cyanides, dichlorophenol,dichlorobenzene, dichloroethane, dichloroethene, dichloropropane,dichloropropene, ethyl alcohol, ethylbenzene, ethylene glycol, ethylmercaptan, hydrogen sulfide, isopropyl alcohol, Lindane™, methylenechloride, methyl tert-butyl ether, naphthalene, nitrobenzene,nitrophenol, pentachlorophenol, phenanthrene, phenol, propylene,propylene glycol, Silvex™, Simazine™, sodium sulfide, tetrachloroethane,tetrachloroethene, toluene, trichlorobenzene, trichloroethane,trichloroethene, trichlorophenol, vinyl chloride, xylene, etc). Many, ifnot most, of these contaminants are organic based and exhibit someproperties similar as oil.

Encapsulant 12 may have a hydrophobic or water resistant compound and issubstantially non-reactive with adjacent reactant 11 and is furthermoresubstantially permeable or dissolvable with at least one targetedorganic compound. Therefore, encapsulant 12 is often desired to be bothsubstantially hydrophobic and substantially oleophilic, since many ifnot most of the targeted compounds exhibit similar properties as oil.Compounds found to have such attributes or properties desired in outerencapsulant 12 include those that comprise polymers of: ethylene,propylene, isobutylene, diisobutylene, styrene, ethylinylbenzene,vinyltoluene, and dicyclopentadiene; esters of acrylic and methacrylicacid, including the methyl, ethyl, propyl, isopropyl, butyl, sec-butyl,tert-butyl, amyl, hexyl, octyl, ethylhexyl, decyl, dedecyl, cyclohexyl,isobornyl, phenyl, benzyl, alkylphenyl, ethoxymenthyl, ethoxyethyl,ethoxypropyl, propoxymethyl, propoxyethyl, propoxpropyl, ethoxphenyl,ethoxybenzyl, and ethoxycyclohexyl esters; vinyl esters, including vinylacetate, vinyl propionate, vinyl butyrate; vinyl ketones, includingvinyl methyl ketone, vinyl ethyl ketone, vinyl isopropyl ketone, andmethyl isopropenyl ketone; vinyl ethers, including vinyl methyl ether,vinyl ethyl ether, vinyl propyl ether, and vinyl isobutyl ether; diallylphthalate, ethylene glycol diacrylate, ethylene glycol dimethacrylate,trimethylolpropanetrimethacrylate, divinylsulfone; polyvinyl andpolyally ethers of ethylene glycol, of glycerol, of pentaerythritol, ofdiethyleneglycol, of monothio- and dithioderivatives of glycols, and ofresorcinol; divinylketone, divinylsulfide, allyl acrylate, diallylmaleate, diallyl fumarate, diallyl succinate, diallyl carbonate, diallylmalonate, diallyl oxalate, diallyl adipate, diallyl sebacate, divinylsebacate, diallyl tartrate, diallyl silicate, triallyl tricarboxylate,triallyl aconitate, triallyl citrate, triallyl phosphate, divinylnaphthalene, divinylbenzene, trivinylbenzene; alkyldivinylbenzeneshaving from 1 to 4 alkyl groups of 1 to 2 carbon atoms substituted onthe benzene nucleus; trivinylnaphthalenes, and/or polyvinylanthracenes,etc., and the like. Other organic compounds such as cellulose, wax (i.e.canola wax), polylactic acid, and combinations and derivatives thereofhave been found to exhibit the desired attributes of outer encapsulant12. These constituents are presented herein as examples of compoundsthat may be incorporated into encapsulant 12 and are not to serve aslimitations on the composition of encapsulant 12.

In certain exemplary embodiments, encapsulant 12 can range fromapproximately 10% to approximately 80% of the total weight ofencapsulated reactant 10. Additionally, for subsurface applications,encapsulant 12 may have an outer dimension of less than 50 or even lessthan 10 μm. Such a configuration is suitable for groundwater treatment.Therefore, embodiments of encapsulated reactant 10 may be referred to asmicroencapsulants. Alternatively, encapsulant 12 may have a large outerdimension of up to an inch, or even more. Such larger size may besuitable for surface water or waste water treatment.

Reactant 11 is selected to react with at least one target constituent inthe media being remediated. Reactant 11 may comprise one or more oxidantconstituents that can comprise: peroxides, permanganates, persulfates,hypochlorite solutions, ozone, and/or fluorine, etc. Peroxide, such ashydrogen peroxide, sodium peroxide, calcium peroxide, potassiumperoxide, and/or magnesium peroxide, etc, has been found effective inoxidizing many organic contaminants. Reactant 11 may comprise an oxidantsuspended in an aqueous catalyst solution comprising a soluble metallicsalt(s) (e.g., ferrous sulfate), chelate(s), and/or buffering agent(s).In certain environments, the aqueous catalyst solution has acircumneutral pH (e.g., a pH of approximately 5.5 to approximately 8.5,including all values and subranges there between). In otherenvironments, an intermediate reaction between the aqueous catalystsolution and reactant 11 can be pH-independent. In still otherenvironments, an intermediate reaction between the aqueous catalystsolution and reactant 11 can be pH-dependent.

FIG. 2 shows a cross-sectional view of an embodiment of encapsulatedreactant 20, made by the process of the present invention, showing afirst reactant 21 and a second reactant 23 within a first encapsulant 22and second encapsulant 24 respectively. Reactant 21 may be a coreoxidant or other reactant while reactant 23 may be the same or adifferent constituent (e.g. a catalyst) trapped between innerencapsulant 22 and the most outer encapsulant 24. In one embodiment ofencapsulated reactant 20, a particle can comprise an inner oxidant core21, surrounded by, yet potentially separated via encapsulant 22 from, anouter catalyst 23 that is surrounded by an outermost encapsulatingcoating 24. Thus, the core oxidant 21 can be segregated from thecatalyst by the internal coating 22, and the catalyst can be segregatedfrom the external environment by the secondary external coating orencapsulant 24. Alternatively, particle or reactant 21 can be an innercatalyst core, surrounded by, yet potentially separated from, an outerencapsulated oxidant 23. Encapsulating multiple constituents into oneparticle can provide a means for ensuring that the encapsulatedconstituents are released within the subterranean environment in thepresence of one another to produce the desired intermediate reaction,and thus, the desired final reaction. This approach can provideparticular utility in heterogeneous subterranean environments thatextend over a relatively large area and/or volume. In this embodiment,encapsulant 24 needs to have similar characteristics as encapsulant 12,since both are exposed to the media that is being treated. However,inner encapsulant 22 may be permeable to water or the media in which itis distributed since it does not contact the media until the mediapenetrates outer encapsulant 24. Therefore, encapsulant 22 only need benon-reactive with reactants 21 and 23.

FIG. 3 shows a cross-sectional view of encapsulated reactant 30, made bythe process of the present invention, showing a first reactant 31 and asecond reactant 32 within a first encapsulant 33. A third reactant 34 isbetween first or inner encapsulant 33 and second encapsulant 35.Reactants 31 and 32 may be a core oxidant or other reactant and acatalyst, chelant, transition metal amine complex, other oxidant, orother reactant. Reactant 34 may be the same or a different constituentthan reactants 31 and 32 trapped between inner encapsulant 33 and themost outer encapsulant 35. Encapsulating multiple constituents orreactants 31, 32, and 34 into one particle or encapsulated reactant 30can provide a means for contacting the reactants 31, 32 34 in a specificsequence to produce the desired intermediate reaction, and thus, thedesired final reaction. In this embodiment, encapsulant 35 needs to havesimilar characteristics as encapsulant 12, since both are exposed to themedia that is being treated. However, inner encapsulant 33 may bepermeable to water or the media in which it is distributed since it doesnot contact the media until the media penetrates outer encapsulant 35.Therefore, encapsulant 33 only need be non-reactive with reactants 31,32 and 34. As shown here, encapsulated reactant 30 can have a variety ofreactants and encapsulants such that an outer encapsulant 35 saves thecontained reactants and encapsulants until encountering a targetconstituent. In such an embodiment, a plurality of reactants, chelants,transition metal amine complexes, and/or catalysts can be introducedinto environment having targeted compounds in a controlled manner with aplurality of encapsulants.

Alternatively or additionally, reactant(s) made by the process of thepresent invention may be placed in a suspension. The reactant(s) may beun-encapsulated or encapsulated. The suspending liquid can be any liquidthat provides for a suspension of reactant(s) in an environment to betreated and has a low oxidation potential with the reactant(s).

The suspended, coated and/or encapsulated reactant(s) described hereinmay be produced by first grinding or comminution: media milling (ballmilling, batch milling, attritor milling, wet or dry processing, etc.);medialess milling (hammer mills, cryogenic hammer mills, jet milling,jaw crushing, high pressure dispersion milling, microfluidization,etc.); screening and/or sieving; air classification, etc. thereactant(s). The reactant(s) may then be encapsulated or coated by spraydrying and prilling; dry powder coating; melt coating, deposition, etc.Alternatively, the reactant(s) are milled in the presence of at leastone coating material to reduce reagglomeration of the reactant(s) duringmilling. Optionally, the at least one coating material provides asuitable coating of the reactant(s) for use in treating theenvironmental media without further coating or encapsulation. Theencapsulated or un-encapsulated reactant(s) may be placed in suspensionor in a slurry prior to placement into the environment to be treated.

The suspended, coated and/or encapsulated reactant(s) made by theprocess of the present invention may be used in treating surface water,groundwater and/or soil in situ or ex situ. For surface water andsurface soil treatment, the suspended, coated and/or encapsulatedreactants are typically placed directly on the zone of contamination orin the path of migration of the contaminants or targeted compounds. Forin situ treatment of groundwater or soil, the suspended, coated and/orencapsulated reactants are typically injected into the zone ofcontamination through a well or direct push techniques. The injectionmay be accomplished by gravity feed or by forcing the reactants into thesubsurface with a pump. In certain exemplary embodiments, the suspended,coated and/or encapsulated reactant(s) made by the process of thepresent invention can be injected (via an aqueous media) into thesubterranean environment at pressures ranging up to approximately 8psig, for example. The injection pressure can be dependent on thesubterranean formation and/or the ability of the subterranean formationto accept the injected solution without substantial subterraneanfractures and/or preferential pathways being created. In somesubterranean formations it may be practical to inject the reactant(s),at a head pressure in excess of 8 psig.

The effective radius and/or path of subterranean influence, in regardsto the above referenced embodiment, can be monitored by utilizing traceragents (e.g., bromide, chloride, rhodamine, flourescein, and/or sulfurhexafluoride, etc.). The tracer can be compatible with site conditionsand/or one or more of the constituents being employed. The tracer can beplaced in the same aqueous media as the encapsulated reactants orparticles and/or within the particles and/or their coating(s) orencapsulant(s). With respect to subterranean background levels (of, forexample, conductivity values and/or specific ion levels), tracerconcentrations preferably range from approximately 10 to 100 timesgreater.

Once the mixture is injected into the subterranean environment,environmental monitoring wells can be monitored and/or sampled fortracer detection (environmental monitoring wells can be strategicallylocated within and/or adjacent to the area(s) of potential chemicalimpact and/or interest). As suggested above, the tracer can be detectedby, for example, monitoring the conductivity levels of the groundwatercompared against native background levels or by utilizing an ionspecific electrode. An effective radius of subterranean influence can beassessed by measuring and/or comparing specific groundwater parameters(e.g., dissolved oxygen levels, oxidation reduction potential, salinity,and/or pH levels, etc.) before, during, and/or after the injectionprocess. Fluctuations in these parameters can be observed insubterranean areas where an oxidation reaction has occurred.

Certain exemplary embodiments can provide a treatment technique for anyand/or all of the above listed chemical contaminant(s) within a varietyof medias and/or subterranean environments comprising: silts, clays,sands, fractured bedrock, karsts, organics, and/or tills. Via certainexemplary embodiments, in situ environmental remediation withinsubsurface bedrock and/or fractured bedrock networks can be greatlyincreased due to the above mentioned adjustable properties of theparticle and/or aqueous mixture.

Alternatively, a trench may be dug down stream of the flow of a plume ofcontamination in the aquifer and filled with the reactants of thepresent invention. In this application, a suspending liquid, coating,and/or outer encapsulant may be designed to remain un-reacted or intactfor an extended period of time (e.g. years) and as the plume ofcontamination passes through the trench, the encapsulant allows thetargeted constituents to react with the reactant(s). Whether injectedinto the subterranean environment or placed in a trench around the plumeof contamination, a reactive oxidant can be kept segregated from ametallic salt(s), chelate(s), and/or buffering agent(s) by internalencapsulation, hence deferring any intermediate reaction there between.Once the desired time or condition of exposure to an aqueous environmenthas elapsed and/or a “triggered” exposure to the contaminant(s) ofconcern has occurred, an outer encapsulant can release the oxidant intothe presence of the metallic salt(s), chelate(s), and/or bufferingagent(s), allowing any intermediate reaction there between to occur, andthereby resulting in the production of oxidizing free radicals, hydroxylradicals, sulfate radicals, or the like possibly by virtue of a mimickedFenton's reaction. The radicals can undergo a final reaction with thecontaminant(s) of concern, oxidizing the contaminant compound(s)(typically exothermically), often times into final products of carbondioxide and water.

The method of using products made by the method of the present inventionmay utilize a combination of one or more reactants. The reactant(s) maybe applied directly, suspended, coated, and/or encapsulated. Thereactant(s) may comprise oxidant(s), metallic salt catalyst(s), and/orchelating agent(s) under conditions which enable oxidation of most, andpreferably substantially all, volatile, semi-volatile, or non-volatileorganic and/or inorganic compounds in soil, rock, sludge, water,groundwater, and/or wastewater (in situ or ex situ) rendering them lessharmful. In one embodiment of the present invention, a combination ofencapsulated oxidant(s) (a persulfate group—potassium or sodium),catalyst(s) (iron salt), and chelating compound(s) (EDTA) are injectedinto the subsurface simultaneously within an aqueous mixture, slurry, orsuspension. For instance, a combination of suspended reactant(s), mayinclude a first group of suspended, coated and/or encapsulated reactantshaving persulfate and a second group of suspended, coated and/orencapsulated reactants having ferrous sulfate. Injection into thesubsurface can be gravity fed or under pressure, both resulting in thedispersion of the reactants within the targeted area of concernincluding both up-gradient and down-gradient placements. The suspended,coated and/or encapsulated reactants of the present invention may remainsubstantially unreactive within the subsurface until contact with thetarget contaminant occurs. Upon contact, the suspending liquids,coatings, and/or encapsulants about the reactants may begin to degrade,weaken, or become more permeable until the reactant contacts the targetcontaminant(s). The oxidant and/or catalyst and/or chelating agent reactindependently or in combination, resulting ultimately in the partial orcomplete oxidation of the target contaminant(s). The final by-productsof the oxidation reaction are typically carbon dioxide, water, a saltgroup (depending on oxidant of choice), and an inorganic chloride ion(if contaminant is chlorinated).

In the embodiment of the invention where the reduced size reactantparticles, un-encapsulated or encapsulated, are placed in suspension orslurry several advantages may be realized. The slurries or suspensionsof the reduced sized reactant particles may serve to overcome a lowsolubility of the reactant(s). For example, the zone of contaminationmay be targeted with a direct application of a concentrated suspensionor slurry, thereby minimizing the total fluid volume required fortreatment application. For example, potassium permanganate has asolubility of about 4% by weight in water. The concentration of thereactant(s) in the slurry may be increased by using different suspendingfluids or by adding surfactants, emulsifiers, or polymeric materials towater to form a suspending liquid, for example. The concentration of thereactant in suspension may be increased to 25%, 50%, or even more. Thisincrease in reactant concentration in suspension may reduce the volumeof the suspension to be injected or placed in the in situ environment.The subterranean formations in the in situ environment may have alimited capacity to accept fluid without displacing the groundwater andcontamination present. Introducing a large volume of suspension orslurry may push contamination further away from its source and furtheraway from the reactant(s). Higher concentrated slurries reduce thevolume to be applied, thus reducing any displacement of thecontaminant(s). Additionally, the more concentrated suspensions orslurries may reduce the injection or application time.

In another selected embodiment of the present invention, a reactanthaving sodium persulfate and optionally a catalyst, e.g. one or moremetallic salts, may be contained within an encapsulant having cellulose,wax, polylactic acid, or combinations or derivatives thereof. Such anembodiment has been found to provide persistence of the reactant(s) inwater until the encapsulated reactants encounter the targeted compoundsat which point the reactant(s) break down the targeted constituentsrendering them less harmful.

The outer coating and/or encapsulant surrounding the reactant(s) may bedesigned to delay the chemical reaction between reactant and targetedcontaminant(s) to allow for an extended coverage area and/or time whenapplied to subsurface treatment. Additionally, the size of theencapsulated reactant can be preselected to allow for less restrictedflow through the subterranean environment, and thereby can provide forextended coverage areas and/or reduced loading restrictions.Encapsulated reactants can also be engineered to rise, sink, and/or besuspended within subterranean aqueous environments by adjusting buoyancyand/or specific gravities of the encapsulated reactant(s) of the presentinvention. Buoyancy can be adjusted by trapping a small gas bubblewithin the encapsulation, to offset the density of one or moreconstituents. A more buoyant (overall density of encapsulation(“solute”) less than aqueous media (“solution”)) encapsulated particlecan be utilized when treating light non-aqueous phase liquid(s)chemical(s) of concern, which can be more abundant toward the upperapproximately 25% of the aqueous media. A less buoyant (overall densityof encapsulation (“solute”) greater than aqueous media (“solution”))encapsulated particle can be utilized when treating dense non-aqueousphase liquid(s) chemical(s) of concern, which can be more abundant inthe lower approximately 25% of the aqueous media.

Another aspect of the present invention is a process for making reducedsized oxidant particles. A coating material that is substantiallyoleophilic, hydrophobic, siliphilic, hydrocarbon soluble, or exhibits acombination of these properties is fed into a mill. The coating materialexhibiting these properties may have a melting point below the operatingtemperature of the mill so that the material is in a liquid state duringmilling. Oxidant particles of an initial or first size are introducedinto the mill and milled. The mill may be a media mill having a mediathat aids in particle size reduction and is separable from the milledoxidant particles. Alternatively, the mill may be a batch mill or othermill. The oxidant particles are milled to a reduced size in the mill.During the milling, the coating material continuously substantiallycoats the oxidant particles, which may reduce reagglomeration of thereduced sized oxidant particles. The particles are milled to a reducedsize, which is smaller than the first or initial size, and may have amean diameter of at most 100 μm, or may be as small as 10 μm, or even 5μm or even less than 1 μm. The milled particles may have a mean diameterof about 1 μm.

The coating material may have a melting point below the operatingtemperature of the mill since a liquid coating material may have agreater propensity to coat the oxidant particles as they are beingmilled. The coating material may be an oil or wax and may be derivedfrom animals, hydrocarbons, vegetables, silicones, or any combinationsthereof. For example, the coating material may be a wax such as paraffinthat may have a melting point above room temperature. Optionally, thecoating material is a combination of oils, waxes, or oils and waxes andmay have a viscosity greater than 0.894 cP or rheology such that theparticles remain substantially suspended in the coating material duringthe milling process. Additionally, the coating material may have amelting point above the operational temperature of the mill and stillexhibit the desired properties of substantially reducing thereagglomeration of the oxidant particles as they are being milled.

EXAMPLES Example 1

Potassium permanganate (KMnO4) was milled in a media mill. The feedstock of KMnO4 had a first particle size of about 100-200 The media millwas manufactured by Custom Milling & Consulting, Inc and had a millingshaft with a plurality of discs extending radially therefrom. The tipspeed of the discs during milling was between about 1800 and 2500 fpm.The milling shaft extended into a cylindrical screen which was enclosedin a jacketed milling chamber. Cerium stabilized zirconium oxide millingmedia having about a 0.8 mm diameter was placed within the screen. Thescreen had slot openings smaller than the diameter of the milling mediaso as to retain the media therein. A discharge from the mixing chamberfed into a jacketed holding vessel. Material was accumulated in theholding vessel and was recirculated back through the mixing chamber. Theparticle size of the milled particles was then measured with a laserscattering analyzer in accordance with ASTM B822.

The milling chamber and holding vessel were heated to a temperature ofabout 125° F. A coating material of hydrogenated soy bean wax was fedinto the media mill. KMnO4 of the first particle size of about 100-200μm was fed into the screen in the milling chamber. The hydrogenated soybean wax and KMnO4 were added to the milling chamber at a weight ratioof about 3:1. The milling shaft was rotated within the screen millingthe KMnO4 for about four hours. An amount of KMnO4 and hydrogenated soybean wax was continually discharged from the milling chamber into theholding vessel where it was recirculated back into the milling chamber.Samples of the milled KMnO4 were collected at 1, 2, 3, and 4 hours atthe point of discharge into the holding vessel and analyzed for particlesize. The particle size of the oxidant particles are shown in Table 1.

Example 2

The milling chamber and holding vessel of Example 1 were heated to atemperature of about 125° F. A coating material of paraffin wax was fedinto the media mill of Example 1. KMnO4 of the first particle size ofabout 100-200 μm was fed into the milling chamber. The paraffin wax andKMnO4 were added to the milling chamber at weight a ratio of about 3:1.The milling shaft was rotated within the screen milling the KMnO4 forabout 3 hours. An amount of KMnO4 and paraffin wax was continuallydischarged from the milling chamber into the holding vessel where it wasrecirculated back into the milling chamber. A sample of the milled KMnO4was collected after 3 hours of milling at the point of discharge intothe holding vessel and analyzed for particle size. The particle size ofthe oxidant particles are shown in Table 1.

Example 3

Coating materials of mineral oil and paraffin wax were fed into a batchmill where the coating materials comprise 95% mineral oil and 5%paraffin. KMnO4 of the first particle size of about 100-200 μm was fedinto the basket in the mill. The coating materials and KMnO4 were addedto the milling vessel at weight a ratio of about 4:1. The KMnO4 wasmilled for about 3.5 hours. A sample of the milled KMnO4 was collectedafter 1, 1.5, 2, 3, and 3.5 hours of milling and analyzed for particlesize. The particle size of the oxidant particles are shown in Table 1.

TABLE 1 Mean oxidant particle size Coating material Hours milled (μm)Hydrogenated soy bean wax 1 2.5 Hydrogenated soy bean wax 2 1.8Hydrogenated soy bean wax 3 1.4 Hydrogenated soy bean wax 4 1.5 Paraffin3 1.6 95% mineral oil, 5% molten 1 5.6 paraffin 95% mineral oil, 5%molten 1.5 4.3 paraffin 95% mineral oil, 5% molten 2 4.5 paraffin 95%mineral oil, 5% molten 3 3.6 paraffin 95% mineral oil, 5% molten 3.5 1.6paraffin

The data of Examples 1, 2, and 3 in Table 1 shows that generally anincrease in milling time decreases oxidant particle size. However, theremay be a minimum obtainable mean particle size for a specific coatingmaterial. For example, a minimum mean particle size was obtained after 3hours in Example 1. At that minimum mean particle size, the additionalmilling may be offset by a tendency of the particles to reagglomerate.However, other or different combinations of coating materials and/orincreased milling time may result in a lower mean particle size, lessthan 1 μm. For example, in Example 3 it was shown generally thatadditional milling of the oxidant particles in a coating material ofmineral oil and paraffin resulted in further reduction of particle size.The selected coating material allows for maximum particle size reductionfor the selected oxidant particle. For example, substantially saturatedhydrocarbons having few or no branches or functional groups may beuseful coating materials for reducing the particle size of permanganatecontaining oxidant particles. Additionally, the mean particle size maybe lowered by maintaining a low moisture content in the environmentsurrounding the oxidant particles and coating material during milling asmoisture may contribute to the tendency of the oxidant particles toreagglomerate. For example, an inert gas such as nitrogen, argon, orcarbon dioxide may be introduced into a housing enclosing the mill.Further other oxidants may be milled to a lower minimum particle size.However, the particle sizes reported here are means as processes in theexamples produced an amount of particles having a particle size of lessthan 1 μm.

Oxidant particles produced by a milling process may be used as areactant without further processing. In this aspect of the invention,the coating material may provide sufficient properties to maintain theoxidant particles in a substantially nonreacted state until contacting atargeted constituent. Alternatively, oxidant particles produced by amilling process may be encapsulated with encapsulating material(s).Additionally, the oxidant particles may be placed in suspension, with orwithout further encapsulation after milling. This suspension of oxidantparticles may be suitable for injection directly into a zone ofcontamination or in a path of migration thereof.

In a yet further embodiment of the present invention, the millingprocess may include reducing the size of an oxidant particle by millingthe oxidant in the presence of a coating material or materials. In thisembodiment, oxidant particle size is reduced by milling an oxidantparticle of a first size in the presence of at least one coatingmaterial to form an oxidant particle of a second size, the second sizebeing at least 10% less than the first size oxidant particle beginningthe milling process. The duration of milling may be adjusted to produceoxidant particles of a desired size.

The present invention provides several advantages over the prior art.The small particle size of the oxidant particles make them suitable forholding in a suspension that may be applied directly into theenvironment to be treated. The optionally provided substantiallyhydrophobic and substantially oleophilic outer encapsulant in theencapsulated reactants of embodiments of the instant invention provide ameans to control the release of reactant(s) until contact occurs withthe targeted contaminants. This provides a highly efficient contaminantdestruction ratio using lesser amounts of oxidant(s), catalyst(s),chelating agents and/or other reactants. Areas of influence, bothhorizontally and vertically, from point of application or injection maybe increased. The reactants provide more capability of controlling thereactant's path of travel or distance since the properties of thecoating material, suspending fluid, and/or outer encapsulant may bemodified. The reactant's size, surface area, buoyancy, specific gravity,density, etc. may be manipulated to engineer encapsulated reactant(s) tofloat, suspend, or sink within the subsurface providing an increasedmeans of reaching targeted contaminants.

One feature or aspect of an embodiment is believed at the time of thefiling of this patent application to possibly reside broadly in aprocess for making reduced sized oxidant particles comprising: feeding acoating material into a mill, the material having a characteristicselected from the group consisting of substantially oleophilic,hydrophobic, siliphilic, hydrocarbon soluble, and combinations thereof;introducing oxidant particles of a first size into the mill; milling theoxidant particles with the material; reducing the particle size of theoxidant particles to the reduced size, the reduced size being less thanthe first size; and coating a substantial portion of each of the reducedsized oxidant particles with the coating material.

Another feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in aprocess for making reduced sized oxidant particles, wherein the reducedsize oxidant particles have a mean diameter of at most 100 μm.

Yet another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly in aprocess for making reduced sized oxidant particles, wherein the reducedsize oxidant particles have a mean diameter of at most 10 μm. Stillanother feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in aprocess for making reduced sized oxidant particles, wherein the reducedsize oxidant particles have a mean diameter of at most 5 μm.

A further feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in aprocess for making reduced sized oxidant particles, wherein the reducedsize oxidant particles have a mean diameter of at most 1 μm.

Another feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in aprocess for making reduced sized oxidant particles, wherein the reducedsize oxidant particles are in a substantially nonoxidized state.

Yet another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly in aprocess for making reduced sized oxidant particles, wherein the mill isa media or batch mill.

Still another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly in aprocess for making reduced sized oxidant particles, wherein the mill ismaintained at a temperature above a melting point of the coatingmaterial.

A further feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in aprocess for making reduced sized oxidant particles, wherein the oxidantparticles have an oxidant selected from the group consisting ofpersulfate, permanganate, peroxygen and combinations thereof.

Another feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly reducedsized oxidant particles formed by the presently disclosed process.

Yet another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly in areduced sized oxidant particles formed by the disclosed process, theparticles having an outermost encapsulant forming an outer surface ofthe oxidant particle, the outermost encapsulant being substantiallynon-reacting, impermeable and non-dissolving with water.

One feature or aspect of an embodiment is believed at the time of thefiling of this patent application to possibly reside broadly in theparticles formed by the disclosed process placed in suspension.

Another feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in aprocess for making oxidant particles comprising: providing solidoxidants of a first size; providing a coating material; feeding theoxidants of a first size and the coating material into a mill; millingthe oxidants of a first size producing milled oxidants; coating themilled oxidants with the coating material; continuing the milling andthe coating steps in the mill until the oxidants of a first size arereduced in size by a sufficient amount to produce the oxidant particles.

Yet another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly inthe process of process for making oxidant particles, wherein the oxidantparticles reduced in size in the mill have a mean diameter of at most100 μm.

Still another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly inthe process of process for making oxidant particles, wherein the coatingmaterial has a characteristic selected from the group consisting ofsubstantially oleophilic, hydrophobic, siliphilic, hydrocarbon soluble,and combinations thereof.

A further feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in theprocess of process for making oxidant particles, wherein the coatingmaterial is in a liquid phase during the milling step.

Another feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in theprocess of process for making oxidant particles, wherein the coatingmaterial is an oil or wax having an origin selected from the groupconsisting of animal, hydrocarbon, vegetable, silicone, and combinationsthereof.

Yet another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly in aprocess for making oxidant particles comprising; feeding at least onecoating material into a mill; feeding at least one oxidant of a firstsize into the mill; milling the at least one oxidant of a first size inthe presence of the at least one coating material to form oxidants of asecond size, the second size being at least 10% less than the firstsize.

Still another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly inthe process for making oxidant particles, wherein the step of feeding atleast one coating material comprises feeding at least two coatingmaterials.

A further feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in theprocess for making oxidant particles, wherein the mill is maintained ata temperature above a melting point of each of the coating materialsduring the milling step.

Another feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in theprocess for making oxidant particles, wherein the at least one coatingmaterial is suitable for substantially coating the at least one oxidantduring the milling step reducing exposure of the at least one oxidant tomoisture.

One feature or aspect of an embodiment is believed at the time of thefiling of this patent application to possibly reside broadly in aprocess for making coated reduced sized oxidant particles consistingessentially of the steps of: heating a mill; feeding a coating materialand oxidant particles into the heated mill, the coating material havinga characteristic selected from the group consisting of substantiallyoleophilic, hydrophobic, siliphilic, hydrocarbon soluble, andcombinations thereof; milling the oxidant particles with the coatingmaterial and thereby reducing the particle size of the oxidant particlesand coating a substantial portion of each of the reduced size oxidantparticles with the coating material, providing the coated reduced sizedoxidant particles; and wherein the mill is maintained at a temperatureabove a melting point of the coating material.

Another feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in theprocess for making coated reduced sized oxidant particles, wherein thereduced size oxidant particles have a mean diameter of at most 100 μm.

Yet another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly inthe process for making coated reduced sized oxidant particles, whereinthe reduced size oxidant particles have a mean diameter of at most 10μm.

Still another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly inthe process for making coated reduced sized oxidant particles, whereinthe reduced size oxidant particles have a mean diameter of at most 5 μm.

A further feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in theprocess for making coated reduced sized oxidant particles, wherein thereduced size oxidant particles have a mean diameter of at most 1 μm.

Another feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in theprocess for making coated reduced sized oxidant particles, wherein thereduced size oxidant particles are in a substantially nonoxidized state.

Yet another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly inthe process for making coated reduced sized oxidant particles, whereinthe mill is a media or batch mill.

Still another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly inthe process for making coated reduced sized oxidant particles, whereinthe oxidant particles have an oxidant selected from the group consistingof persulfate, permanganate, peroxygen, and combinations thereof.

A further feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in aprocess for making coated oxidant particles comprising the of the stepsof: providing solid oxidants of a first size; providing a coatingmaterial; heating a mill; feeding the oxidants of a first size and thecoating material into the heated mill; milling the oxidants of a firstsize producing milled oxidants; coating the milled oxidants with thecoating material; continuing the milling and the coating steps in themill until the oxidants of a first size are reduced in size by asufficient amount to produce the coated oxidant particles; and whereinthe coating material is maintained in a liquid phase during the millingstep.

Another feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in theprocess for making coated oxidant particles, wherein the coated oxidantparticles reduced in size in the mill have a mean diameter of at most100 μm.

Yet another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly inthe process for making coated oxidant particles, wherein the coatingmaterial has a characteristic selected from the group consisting ofsubstantially oleophilic, hydrophobic, siliphilic, hydrocarbon soluble,and combinations thereof.

One feature or aspect of an embodiment is believed at the time of thefiling of this patent application to possibly reside broadly in theprocess for making coated oxidant particles, wherein the coatingmaterial is an oil or wax having an origin selected from the groupconsisting of animal, hydrocarbon, vegetable, silicone, and combinationsthereof.

Another feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in aprocess for making coated oxidant particles comprising; heating a mill;feeding at least one coating material into the heated mill; feeding atleast one oxidant of a first size into the heated mill; milling the atleast one oxidant of a first size in the presence of the at least onecoating material to form oxidants of a second size, the second sizebeing at least 10% less than the first size; substantially coating theoxidants of a second size with the at least one coating material, duringthe milling step, and providing the coated oxidant particles; andwherein the coating material has a melting point below the operationaltemperature of the mill.

Yet another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly inthe process for making coated oxidant particles, wherein the step offeeding at least one coating material comprises feeding at least twocoating materials.

Still another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly inthe process for making coated oxidant particles, wherein the at leastone coating material is suitable for substantially coating the at leastone oxidant throughout the milling step and thereby reducing exposure ofthe at least one oxidant to moisture.

A further feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in theprocess for making coated oxidant particles, wherein the coatingmaterial is a combination of oils, waxes, or oils and waxes having aviscosity greater than 0.894 cP at the operational temperature of themill.

Another feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in theprocess for making coated oxidant particles, wherein the second size isless than 2 micrometers.

In at least one embodiment of the present disclosure, the reactant(s)may be encapsulated with an encapsulant by procedures such as forexample high temperature extrusion or molding, tabletting,microencapsulation, to formulate them into their final shapes, beforeadministration.

In at least one other embodiment of the present disclosure, thereactant(s) may be coated with the encapsulant to form any shape. Forexample, encapsulated reactants of the present disclosure may be formedby techniques well known in the art, such as spray drying or prilling,by extrusion or compression in molds, or by a agglomeration of finepowders in rotating drums using a liquid phase binder, or encapsulant,and/or heat.

In at least one further embodiment of the present disclosure, theencapsulated reactant of the present disclosure may be made by meltingthe encapsulant, mixing the reactant(s) into the melted encapsulant, andcooling the mixture to form a solid mass of encapsulate reactant. Themixture may be cooled in a mold to form any desired shape of theencapsulated reactant.

One feature or aspect of an embodiment is believed at the time of thefiling of this patent application to possibly reside broadly anencapsulated reactant for insertion into a subterranean zone ofcontamination which is contaminated by a targeted contaminant, theencapsulated reactant comprising: a plurality of reactant particles; anda single encapsulant encapsulating each of the reactant particles,wherein the mass of the single encapsulant ranges from about 10% toabout 80% of the total mass of the encapsulated reactant, wherein theencapsulated reactant has an outer dimension greater than one inch; andwherein the encapsulated reactant is of sufficient size and mass suchthat it does not flow through the subterranean zone of contaminationwhen inserted therein.

Another feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in theencapsulated reactant, wherein the single encapsulant comprises asubstantially oleophilic compound.

Yet another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly inthe encapsulated reactant, wherein the substantially oleophilic compoundcomprises a constituent selected from the group consisting of cellulose,wax, polylactic acid, and combinations and derivatives thereof.

Still another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly inthe encapsulated reactant, wherein the single encapsulant is adapted tobe capable of being degraded, weakened, or permeated by the targetedcontaminant.

A further feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in theencapsulated reactant, wherein the single encapsulant comprises acomponent adapted to provide for accelerated degradation of the singleencapsulant upon contact with the targeted compound.

Another feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in theencapsulated reactant, wherein each of the plurality of reactantparticles comprises an oxidant.

Yet another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly inthe encapsulated reactant, wherein the oxidant comprises a chemicalmoiety selected from the group consisting of persulfate, permanganate,and peroxygen.

Still another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly inthe encapsulated reactant, wherein the oxidant is potassiumpermanganate.

A further feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in theencapsulated reactant, wherein the reactant is reactive with thetargeted contaminant such that it degrades the target contaminant.

Another feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in theencapsulated reactant, wherein the size and mass of the encapsulatedreactant are adapted to allow the encapsulated reactant to float,suspend or sink within a subsurface of the earth.

Yet another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly in aprocess of making a solid encapsulated reactant suitable for placementin a subterranean zone of contamination which is contaminated by atarget encapsulant, the process comprising: preparing an encapsulant bymelting a mass of the encapsulant to convert the encapsulant to anon-solid state thereby making a prepared encapsultant; combining aplurality of reactant particles with the prepared encapsulant therebymelt coating the plurality of reactant particles with the preparedencapsulant thereby making an encapsulated reactant; and cooling theencapsulated reactant thus forming the solid encapsulated reactant,wherein the solid encapsulated has an outer dimension of at least oneinch, further wherein the solid encapsulated reactant is of sufficientsize and mass such that it does not flow through the subterranean zoneof contamination.

Another feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in theprocess of making a solid encapsulated reactant, wherein the preparedencapsulant comprises a substantially oleophilic compound.

Yet another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly inthe process of making a solid encapsulated reactant, wherein thesubstantially oleophilic compound comprises a constituent selected fromthe group consisting of cellulose, wax, polylactic acid, andcombinations and derivatives thereof.

Still another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly inthe process of making a solid encapsulated reactant, wherein theprepared encapsulant is adapted to be capable of being degraded,weakened, or permeated by the targeted contaminant.

A further feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in theprocess of making a solid encapsulated reactant, wherein the preparedencapsulant comprises a component adapted to provide for accelerateddegradation of the single encapsulant upon contact with the targetedcompound.

Another feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in theprocess of making a solid encapsulated reactant, wherein each of theplurality of reactant particles comprises an oxidant.

Yet another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly inthe process of making a solid encapsulated reactant, wherein the oxidantcomprises a chemical moiety selected from the group consisting ofpersulfate, permanganate, and peroxygen.

Still another feature or aspect of an embodiment is believed at the timeof the filing of this patent application to possibly reside broadly inthe process of making a solid encapsulated reactant, wherein the oxidantis potassium permanganate.

A further feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly in theprocess of making a solid encapsulated reactant, wherein the reactant isreactive with the targeted contaminant such that it degrades the targetcontaminant.

Another feature or aspect of an embodiment is believed at the time ofthe filing of this patent application to possibly reside broadly i inthe process of making a solid encapsulated reactant, wherein the sizeand mass of the encapsulated reactant are adapted to allow theencapsulated reactant to float, suspend or sink within a subsurface ofthe earth.

The invention claimed is:
 1. A sustained release reactant blend fortreating a medium containing a contaminant, the sustained releasereactant blend comprising: a solid reactant blend comprising a firstreactant; a second reactant; and a matrix, wherein at least one of thefirst and second reactant is substantially coated by the matrix to forma substantially coated reactant; wherein the solid reactant blend isdefined by a structure such that the medium and contaminant can flowinto the structure and contact the substantially coated reactant; andwherein the first reactant and the second reactant provide for asustained reactant release over a time period that is at least onemonth.
 2. The sustained release reactant blend of claim 1, wherein thefirst reactant is potassium permanganate.
 3. The sustained releasereactant blend of claim 1, wherein the first reactant is sodiumpersulfate.
 4. The sustained release reactant blend of claim 1, whereinthe matrix is insoluble and biodegradable.
 5. The sustained releasereactant blend of claim 1, wherein the sustained reactant releaseincreases when a surface area of the sustained release reactant blend isincreased.
 6. The sustained release reactant blend of claim 1, whereinthe matrix is paraffin wax.
 7. The sustained release reactant blend ofclaim 6, wherein the paraffin wax provides a coating for the firstreactant and the second reactant such that the sustained releasereactant blend is a structured mass.
 8. The sustained release reactantblend of claim 7, wherein the sustained reactant release increases whena surface area of the sustained release reactant blend is increased. 9.A process for making a combined sustained release reactant having asolid reactant blend, the process comprising: selecting a firstreactant; selecting a second reactant; preparing a matrix, the preparedmatrix capable of coating the first reactant and the second reactant;combining the first reactant, the second reactant, and the preparedmatrix by mixing to make a combination; and forming the combinedsustained release reactant into the solid reactant blend; wherein thecombined sustained release reactant has a structure; wherein at leastone of the first and second reactant is substantially coated by thematrix; and wherein the first reactant and the second reactant providefor a sustained reactant release over a time period that is at least onemonth.
 10. The process of claim 9, wherein the first reactant ispotassium permanganate.
 11. The process of claim 9, wherein the firstreactant is sodium persulfate.
 12. The process of claim 9, wherein thematrix is paraffin wax.
 13. The process of claim 9, wherein thesustained reactant release increases when a surface area of the combinedsustained release reactant is increased.